Determination of the concentration of petroleum products and oils in filmsat the surface of water using a solid-electrolyte analyzer

Citation
Bk. Zuev et al., Determination of the concentration of petroleum products and oils in filmsat the surface of water using a solid-electrolyte analyzer, J ANALYT CH, 56(5), 2001, pp. 481-484
Citations number
14
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF ANALYTICAL CHEMISTRY
ISSN journal
10619348 → ACNP
Volume
56
Issue
5
Year of publication
2001
Pages
481 - 484
Database
ISI
SICI code
1061-9348(200105)56:5<481:DOTCOP>2.0.ZU;2-E
Abstract
A method was proposed for estimating the total amount of organic substance at the air-water interface. The method combines sampling by the transfer of an organic film to the probe surface with the coulometric determination of the amount of oxygen consumed for the high-temperature oxidation of the sa mple in a solid-electrolyte analyzer. The effect of the composition of the him and the material of the probe on the transfer of model oil films under the conditions of fast withdrawal of the probe From water was studied. It w as demonstrated that organic substance can be accumulated at the surface of the probe on multiple withdrawal.