New indicator reactions involving sulfur-containing organic compounds for the kinetic determination of selenium

Citation
Ar. Garifzyanov et al., New indicator reactions involving sulfur-containing organic compounds for the kinetic determination of selenium, J ANALYT CH, 56(5), 2001, pp. 485-488
Citations number
5
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF ANALYTICAL CHEMISTRY
ISSN journal
10619348 → ACNP
Volume
56
Issue
5
Year of publication
2001
Pages
485 - 488
Database
ISI
SICI code
1061-9348(200105)56:5<485:NIRISO>2.0.ZU;2-1
Abstract
New indicator reactions were proposed for the determination of selenium by the kinetic method based on the reduction of Methylene Blue by some sulfur- containing organic compounds. It was demonstrated that a high sensitivity o f the determination of selenium is attained using unithiol and thiomalic, 2 ,3-dithiomercaptopropionic, and rubeanic acids as reducing agents. In the p resence of unithiol, down to 4 ng/mL selenium can be determined.