S. Dev et K. Ismail, Electrical conductance of sodium dodecyl sulfate in calcium nitrate tetrahydrate plus acetamide melts, J CHEM EN D, 46(3), 2001, pp. 574-576
The specific conductance of sodium dodecyl sulfate (SDS) in molten mixtures
of calcium nitrate tetrahydrate (CNTH) and acetamide was measured at 38 de
greesC. In these molten mixtures SDS undergoes micellization and the values
of the critical micelle concentration (cmc) were estimated. The shape of t
he specific conductance versus concentration of SDS isotherm depends on the
relative amounts of the hydrated salt and acetamide present in the molten
mixture. The slope of this isotherm is positive in the acetamide-rich (>sim
ilar to 73 mass % acetamide) melt, and it changes to a negative value in th
e hydrated salt-rich melt.