A new carboxylic acid with branched ponytails for the solubilization of Mn(II) and Co(II) ions in perfluorocarbons

Authors
Loiseau, J Fouquet, E Fish, RH Vincent, JM Verlhac, JB
Citation
J. Loiseau et al., A new carboxylic acid with branched ponytails for the solubilization of Mn(II) and Co(II) ions in perfluorocarbons, J FLUORINE, 108(2), 2001, pp. 195-197
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
108
Issue
2
Year of publication
2001
Pages
195 - 197
Database
ISI
SICI code
0022-1139(200105)108:2<195:ANCAWB>2.0.ZU;2-5
Abstract
The synthesis of a carboxylic acid (C8F17(CH2)(3))(2)CHCOOH 3 bearing two l ong branched perfluoroalkyl-alkyl chains is described. This acid is highly soluble in perfluorocarbons and is 3 useful ligand fur the preparation of t ransition metal complexes that are soluble in fluorinated media. This is il lustrated by the preparation of the manganese(II)- and cobalt(II)-carboxyla te: complexes, both of which are soluble in perfluorocarbons and are thus p otentially interesting starting materials for metal-catalyzed reactions und er fluorous biphasic procedures. (C) 2001 Elsevier Science B.V. All rights reserved.