The phase diagram of the La2O3-Ta2O5-Ga2O3 system around La3Ta0.5Ga5.5O14 (
LTG) was investigated by a differential thermal analysis and the quenching
method. La3Ta0.5Ga5.5O14 single crystals were subsequently grown from diffe
rent starting melt compositions using the Czochralski technique. The effect
of the starting melt composition on crystal quality was examined by measur
ing the variation in the chemical composition and lattice parameters along
the growth axis. On the basis of these experimental results, we have grown
LTG single crystals over 2 inches in diameter. (C) 2001 Kluwer Academic Pub
lishers.