A QSRR treatment of solvent effects on the decarboxylation of 6-nitrobenzisoxazole-3-carboxylates employing molecular descriptors

Authors
Katritzky, AR Perumal, S Petrukhin, R
Citation
Ar. Katritzky et al., A QSRR treatment of solvent effects on the decarboxylation of 6-nitrobenzisoxazole-3-carboxylates employing molecular descriptors, J ORG CHEM, 66(11), 2001, pp. 4036-4040
Citations number
15
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
00223263 → ACNP
Volume
66
Issue
11
Year of publication
2001
Pages
4036 - 4040
Database
ISI
SICI code
0022-3263(20010601)66:11<4036:AQTOSE>2.0.ZU;2-G
Abstract
A quantitative structure-reactivity relationship (QSRR) study of the decarb oxylation rates of 6-nitrobenzisoxazole-3-carboxylic acid (Kemp, D. S.; Pau l, K. G. J. Am. Chem. Sec. 197.5, 97, 7305). employing the CODESSA program correlates the effect of 24 solvents with theoretical descriptors to provid e a straightforward interpretation of these solvent effects in terms of mol ecular parameters.