Stable Ti/IrOx-Sb2O5-SnO2 anode for O-2 evolution with low Ir content

Titanium anodes coated with a ternary iridium, antimony, and tin oxide mixt ure (Ti/IrOx-Sb2O5-SnO2) were investigated for oxygen evolution. In the act ive oxide coating, SnO2 serves as a dispersing agent, Sb2O5 as a dopant, an d IrOx as a catalyst. Experimental results showed that the Ti/LrOx-Sb2O5-Sn O2 electrode containing only 10 mol % of IrOx nominally in the coating had a service life of 1600 h in 3 M H2SO4 solution under a current density of 1 A cm(-2) at 35 degreesC, compared with 355 h for Ti/IrOx under the same co nditions. Instrumental analysis indicated that the IrOx-Sb2O5-SnO2 was a me tastable solid solution with a compact structure, which contributes to the superstable nature of the electrode together with the good conductivity and the improvement of bonding with the TiO2 interlayer formed during calcinat ion.