Thermodynamic properties of the mixture acetone plus methanol plus n-octane at 25 degrees C

Citation
M. Iglesias et al., Thermodynamic properties of the mixture acetone plus methanol plus n-octane at 25 degrees C, J SOL CHEM, 30(2), 2001, pp. 133-148
Citations number
19
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF SOLUTION CHEMISTRY
ISSN journal
00959782 → ACNP
Volume
30
Issue
2
Year of publication
2001
Pages
133 - 148
Database
ISI
SICI code
0095-9782(200102)30:2<133:TPOTMA>2.0.ZU;2-C
Abstract
Mixing properties of the ternary mixture acetone + methanol + n-octane have been determined experimentally under standard conditions. Sound velocity, densities, and refractive indexes were measured as functions of composition . Excess molar volumes, changes of refractive indexes, and changes of isent ropic compressibilities on mixing were computed from the experimental data. The Peng-Robinson and Soave-Redlich-Kwong equations of state were applied with three different mixing rules to correlate binary excess volumes and th en to predict the excess magnitudes in ternary mixtures. Reliable represent ations of the experimental data were obtained.