Thermodynamic properties of the ternary system potassium bromide plus lithium bromide plus water at 25 degrees C

Citation
Wd. Yan et al., Thermodynamic properties of the ternary system potassium bromide plus lithium bromide plus water at 25 degrees C, J SOL CHEM, 30(2), 2001, pp. 193-200
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF SOLUTION CHEMISTRY
ISSN journal
00959782 → ACNP
Volume
30
Issue
2
Year of publication
2001
Pages
193 - 200
Database
ISI
SICI code
0095-9782(200102)30:2<193:TPOTTS>2.0.ZU;2-7
Abstract
Activity coefficients of potassium bromide in aqueous mixtures of potassium bromide and lithium bromide were determined by emf measurement at 25 degre esC and at six ionic strengths from 0.1 to 2.5 mol . kg(-1). The experiment al data were fitted using the Scatchard-Rush-Johnson and Fitter models. The osmotic coefficients. excess Gibbs: energies of mixing, and activity coeff icients of lithium bromide in aqueous mixtures were calculated using Pitzer mixing parameters obtained in this work.