A novel utilization of trifluoromethanide as a base: a convenient synthesis of trimethylsilylacetylene

Authors
Yoshimatsu, M Kuribayashi, M
Citation
M. Yoshimatsu et M. Kuribayashi, A novel utilization of trifluoromethanide as a base: a convenient synthesis of trimethylsilylacetylene, J CHEM S P1, (11), 2001, pp. 1256-1257
Citations number
21
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
14727781 → ACNP
Issue
11
Year of publication
2001
Pages
1256 - 1257
Database
ISI
SICI code
1472-7781(2001):11<1256:ANUOTA>2.0.ZU;2-5
Abstract
Trifluoromethanide generated from CF3SiMe3-Bu4NF reacted with terminal acet ylenes and acetylenic selenides as a base or a nucleophile to give trimethy lsilylacetylenes in high yields.