Wmm. Kessels et al., Improvement of hydrogenated amorphous silicon properties with increasing contribution of SiH3 to film growth, J VAC SCI A, 19(3), 2001, pp. 1027-1029
From cavity ring down spectroscopy and threshold ionization mass spectromet
ry measurements in a remote Ar-H-2-SiH4 plasma it is clearly demonstrated t
hat the properties of hydrogenated amorphous silicon (a-Si:H) strongly impr
ove with increasing contribution of SiH3 to film growth. The measurements c
orroborate the proposed dissociation reactions of SiH4 for different plasma
settings and it is shown that film growth is by far dominated by SiH3 unde
r conditions for which solar grade quality a-Si:H at deposition rates up to
10 nm/s has previously been reported. (C) 2001 American Vacuum Society.