Liquid bridges in chemically structured slit pores

Citation
A. Valencia et al., Liquid bridges in chemically structured slit pores, LANGMUIR, 17(11), 2001, pp. 3390-3399
Citations number
27
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LANGMUIR
ISSN journal
07437463 → ACNP
Volume
17
Issue
11
Year of publication
2001
Pages
3390 - 3399
Database
ISI
SICI code
0743-7463(20010529)17:11<3390:LBICSS>2.0.ZU;2-V
Abstract
Wetting phenomena are theoretically studied for a slit pore or slab geometr y between two structured surfaces which contain stripes of lyophilic surfac e domains. Two different approaches are used and compared: Monte Carlo simu lations of lattice gas models and minimization methods applied to effective interface models. Both types of calculations show that the wetting liquid often attains anvil-like bridges which are not translationally invariant pa rallel to the surface stripes. As a control parameter such as the Liquid vo lume or the surface separation is changed, these bridges undergo morphologi cal wetting transitions to symmetric or asymmetric channel states.