New synthetic route in obtaining copper chromite I. Hydrolysis of some soluble salts

Authors
Patron, L Pocol, V Carp, O Modrogan, E Brezeanu, M
Citation
L. Patron et al., New synthetic route in obtaining copper chromite I. Hydrolysis of some soluble salts, MATER RES B, 36(7-8), 2001, pp. 1269-1276
Citations number
13
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
MATERIALS RESEARCH BULLETIN
ISSN journal
00255408 → ACNP
Volume
36
Issue
7-8
Year of publication
2001
Pages
1269 - 1276
Database
ISI
SICI code
0025-5408(200105/06)36:7-8<1269:NSRIOC>2.0.ZU;2-J
Abstract
The possibility of obtaining copper chromite through thermal decomposition of some polynuclear coordination compounds. [Cr2Cu(NH3)(2)(OH)(6)](NO3)(2) and [Cr2Cu(OH)(8)]. 4H(2)O obtained through hydrolytic decomposition of chr omium and copper soluble salts was considered. A decomposition mechanism of the pattern compounds is proposed. A pure tetragonal Cr2CuO4 with mean cry stallite sizes varying in the range 133-210 Angstrom was obtained between t he temperature limits 823 K-1073 K. (C) 2001 Elsevier Science Ltd. All righ ts reserved.