Optical properties of Ta(3-x)Zr(x)N(5-x)O(x) semiconductor pigments

Tantalum zirconium oxynitride phases Ta(3-x)Zr(x)N(5-x)O(x) (0 less than or equal to x less than or equal to 0.66) having the Ta3N5 structure and Ta(1 -x)Zr(x)N(1-x)O(1+x) (0 less than or equal to x less than or equal to 0.28) with the TaON structure have been prepared by solid state-gas syntheses, O xide precursors have been prepared by a novel sol-gel process variant, usin g a mixture of acetic acid and acetic anhydride as solvent. The optical pro perties of the brilliantly coloured pigment quality Ta(3-x)Zr(x)N(5-x)O(x) (0 less than or equal to x less than or equal to 0.66) semiconducting oxyni trides have been examined by UV-VIS remission spectroscopy. Their applicabi lity for an industrial scale production and a widespread use as brilliant, lightfast and inert inorganic colouring agents has been investigated. These pigments may be useful for colouring paints, plastics and medium temperatu re ceramic applications, replacing comtemporary toxic metal containing pigm ents. (C) 2001 Elsevier Science Ltd, All rights reserved.