The fracture and plastic deformation mechanisms of a Zr-Ti-Ni-Cu-Be bulk me
tallic glass and a composite utilizing a crystalline reinforcement phase ar
e reviewed. The relationship between stress state? free volume and shear ba
nd formation are discussed. Positron annihilation techniques were used to c
onfirm the predicted increase in free volume after plastic straining. Strai
n localization and failure were examined for a wide range of stress states.
Finally, methods for toughening metallic glasses are considered. Significa
nt increases in toughness are demonstrated for a composite bulk metallic gl
ass containing a ductile second phase which stabilizes shear band formation
and distributes plastic deformation.