The leachability of antimony and arsenic from Peruvian complex sulfide conc
entrates (Casapalca, Huaron) were studied by alkaline Na2S leaching. The ex
periments have shown that by a proper mechanical activation of the difficul
t to treat concentrates 99% Sb and 99% As from Casapalca and 63% Sb and 80%
As from Huaron can be eliminated. The chemical composition of CuPbZnAg con
centrates after Sb and As elimination may improve the further pyrometallurg
ical treatment from the technological as well as environmental aspects.