Structural, CV and IR spectroscopic evidences for preorientation in PET-active phthalimido carboxylic acids

Authors
Oelgemoller, M Griesbeck, AG Lex, J Haeuseler, A Schmittel, M Niki, M Hesek, D Inoue, Y
Citation
M. Oelgemoller et al., Structural, CV and IR spectroscopic evidences for preorientation in PET-active phthalimido carboxylic acids, ORG LETT, 3(11), 2001, pp. 1593-1596
Citations number
44
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
11
Year of publication
2001
Pages
1593 - 1596
Database
ISI
SICI code
1523-7060(20010531)3:11<1593:SCAISE>2.0.ZU;2-T
Abstract
[GRAPHICS] X = H, K Hydrogen bond and potassium cation mediated preorientation were detected fo r phthalimido acetic acid and the corresponding acetate. Evidence for these phenomena came from X-ray structure analysis as well as cyclic voltammetri c and IR spectroscopic measurements. These interactions rationalize the pho toinduced electron transfer (PET) reactivity of the substrates in photodeca rboxylation reactions.