In situ oxidation-imine formation-reduction routes from alcohols to amines

Authors
Blackburn, L Taylor, RJK
Citation
L. Blackburn et Rjk. Taylor, In situ oxidation-imine formation-reduction routes from alcohols to amines, ORG LETT, 3(11), 2001, pp. 1637-1639
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
11
Year of publication
2001
Pages
1637 - 1639
Database
ISI
SICI code
1523-7060(20010531)3:11<1637:ISOFRF>2.0.ZU;2-Y
Abstract
[GRAPHICS] Manganese dioxide is employed as an in situ oxidant for the one pot convers ion of alcohols into imines, In combination with polymer-supported cyanobor ohydride (PSCBH), a one-pot oxidation-imine formation-reduction sequence is reported, This procedure enables alcohols to be converted directly into bo th secondary and tertiary amines.