Lm. Wang et al., Comparison of structural relaxation of Pd39Ni10CU30P21 bulk metallic glassunder ambient pressure and at a high pressure, PHIL MAG L, 81(6), 2001, pp. 419-423
Structural relaxations of a Pd39Ni10Cu30P21 bulk metallic glass (BMG) under
ambient pressure and at a high pressure are compared by means of temperatu
re-modulated differential scanning calorimetry (TMDSC) measurements. The st
ructural relaxation is evaluated by the enthalpy recovery involved upon pas
sing through the glass transition in the irreversible TMDSC curves. It is f
ound that the isothermal relaxation of the BMG under ambient pressure leads
to a lower-enthalpy state than that under a high pressure. The onset tempe
rature for the enthalpy recovery process is found to exhibit a linear depen
dence on the recovery enthalpy.