M. Cocchi et al., Density and volume properties of the 2-methoxyethanol+1,2-dimethoxyethane plus water ternary solvent system at various temperatures, PHYS CHEM L, 39(2), 2001, pp. 151-168
Densities (rho) of the ternary mixtures 2-methoxyethanol + 1,2-dimethoxyeth
ane + water have been measured at 19 temperatures in the range -263.15 less
than or equal toT/K less than or equal to 353.15. The experimental data we
re processed by empirical relations accounting for the dependence of rho on
temperature and ternary composition expressed as mole fraction of the comp
onents (0 less than or equal to x(i) less than or equal to 1). All checked
equations seem to be suitable for correlation purposes, in order to obtain
interpolated values in correspondence to experimental data gaps. Furthermor
e, the excess molar volume (V-E) has been investigated to make evident the
possibility of forming stable solvent-cosolvent adducts. The excess propert
y has been interpreted on the basis of specific intermolecular interactions
between the components.