Solubility of anthracene in binary alkane+2-methyl-2-propanol solvent mixtures at 298.2 K

Citation
Km. De Fina et al., Solubility of anthracene in binary alkane+2-methyl-2-propanol solvent mixtures at 298.2 K, PHYS CHEM L, 39(2), 2001, pp. 249-254
Citations number
5
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICS AND CHEMISTRY OF LIQUIDS
ISSN journal
00319104 → ACNP
Volume
39
Issue
2
Year of publication
2001
Pages
249 - 254
Database
ISI
SICI code
0031-9104(2001)39:2<249:SOAIBA>2.0.ZU;2-X
Abstract
Experimental solubilities are reported for anthracene dissolved in four bin ary alkane + 2-methyl-2-propanol solvent mixtures at 25 degreesC. The alkan e cosolvents studied were n-heptane, cyclohexane, methylcyclohexane and 2,2 ,4-trimethylpentane. Results of these measurements are used to test two mat hematical representations based upon the combined Nearly Ideal Binary Solve nt (NIBS)/Redlich-Kister and Modified Wilson equations. For the four system s studied, the Combined NIBS/Redlich-Kister equation was found to provide t he better mathematical representation of the experimental data, with overal l average absolute deviations between measured and calculated values being approximately +/-0.5%. Slightly larger deviations were noted in the case of the Modified Wilson equation.