Use of advanced techniques to model the dispersion of chlorine in complex terrain

Citation
Ma. Mcbride et al., Use of advanced techniques to model the dispersion of chlorine in complex terrain, PROCESS SAF, 79(B2), 2001, pp. 89-102
Citations number
19
Categorie Soggetti
Chemical Engineering
Journal title
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
ISSN journal
09575820 → ACNP
Volume
79
Issue
B2
Year of publication
2001
Pages
89 - 102
Database
ISI
SICI code
0957-5820(200103)79:B2<89:UOATTM>2.0.ZU;2-0
Abstract
he EU Seveso II Directive requires operators of major hazard facilities to prepare safety reports for sites storing quantities of dangerous substances in excess of specified levels. The safety report should include an assessm ent of the risk associated with the facility, which will include an evaluat ion of the effects of releases of dangerous substances to the environment. The models commonly used fur assessing the dispersion of dense gases in the atmosphere are based on the 'ideal' of flat, unobstructed terrain. For 're al' situations such models may be unduly pessimistic in their predictions a nd, in certain circumstances, may even be optimistic. This paper describes work undertaken by Environmental Resources Management (ERM), in association with sub-consultants Rowan Williams Davies & Irwin Inc. (RWDI) and the Hea lth and Safety Laboratory (HSL) to model the dispersion of chlorine in comp lex terrain. The work involved physical modelling of releases in a Boundary Layer Wind Tunnel (BLWT) and the use of Computational Fluid Dynamics (CFD) . The paper focuses on the key findings of the study, which provide a drama tic insight into how terrain and buildings can fundamentally alter the disp ersion behaviour of dense gases. The results show how flat tel rain models may overestimate the chlorine hazard range by as much as a factor of 5, whi lst the predicted direction of travel of the cloud may err by up to 90 degr ees. This has implications not only for the assessment of risks associated with major hazard facilities, but also for land-use planning in the vicinit y of the site and emergency preparedness.