Anodic polymerization of aluminum tetraaminophthalocyanine and electrocatalysis of this process by polymer perfluorinated cation exchanger MF4-SK

Authors
Alpatova, NM Ovsyannikova, EV Topolev, VV Tomilova, LG Kogan, EG Berezina, NP Bobrova, LP Timofeev, SV
Citation
Nm. Alpatova et al., Anodic polymerization of aluminum tetraaminophthalocyanine and electrocatalysis of this process by polymer perfluorinated cation exchanger MF4-SK, RUSS J ELEC, 37(5), 2001, pp. 443-447
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
ISSN journal
10231935 → ACNP
Volume
37
Issue
5
Year of publication
2001
Pages
443 - 447
Database
ISI
SICI code
1023-1935(200105)37:5<443:APOATA>2.0.ZU;2-S
Abstract
Anodic polymerization of aluminum tetraaminophthalocyanine chloride on cond ucting glasses in dimethylformamide containing Bu4NBF4 and the effect of ca tion exchanger MF4-SK on this process are studied. The polymer accumulation , monitored from optical absorption spectra, shows that introducing MF4-SK into solution or depositing it as a solid layer on the electrode accelerate s the polymerization by a factor of four to six.