Electrode processes involving associates of CoNTA(-) and CoEDTA(2-) with hexacyanoferrate ions in aqueous solutions

Authors
Kotov, VY Tsirlina, GA Perfil'ev, YD Kim, TG Kostina, SA
Citation
Vy. Kotov et al., Electrode processes involving associates of CoNTA(-) and CoEDTA(2-) with hexacyanoferrate ions in aqueous solutions, RUSS J ELEC, 37(5), 2001, pp. 455-461
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
ISSN journal
10231935 → ACNP
Volume
37
Issue
5
Year of publication
2001
Pages
455 - 461
Database
ISI
SICI code
1023-1935(200105)37:5<455:EPIAOC>2.0.ZU;2-O
Abstract
Ionic association in K3Fe(CN)(6) solutions containing cobalt(II) ethylenedi aminetetraacetate and nitrilotriacetate is studied by voltammetry, spectrop hotometry, and Mossbauer, IR, and Co-59 NMR spectroscopy techniques. Situat ions where the inner-sphere association leads to the formation of solid pro ducts on electrodes (conducting films among them) are revealed.