Cc. Chang et al., ELECTROOPTICAL STUDY OF NEMATIC ELASTOMER GELS, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 56(1), 1997, pp. 595-599
We report on an electro-optical study of a liquid-crystal-polymer comp
osite system. This system is made by dissolving a small amount of acry
late monomers (8%) plus crosslinkers in a nematic liquid crystal, and
then photopolymerizing the homogeneous mixture. These nematic gels sho
w properties different from those of ordinary nematics or polymer stab
ilized liquid crystals. By studying the electric field induced Frederi
ks transition, some basic propel-ties of the nematic gels can be deduc
ed. We compare the experimental results to a simple phenomenological m
odel of the nematic gel, involving a characteristic length scale of or
der 1 mu m, which is also visible as speckles, an effective internal a
ligning field of a few statvolts per cm, and an increased rotational v
iscosity on the order of 10(4) P. We indicate how a microscopic model
might relate the first two of these parameters.