PARTIAL INTEGRATION AND LOCAL MEAN-FIELD APPROACH FOR A VECTOR LATTICE MODEL OF MICROEMULSIONS

Citation
C. Buzano et al., PARTIAL INTEGRATION AND LOCAL MEAN-FIELD APPROACH FOR A VECTOR LATTICE MODEL OF MICROEMULSIONS, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 56(1), 1997, pp. 770-779
Citations number
23
Categorie Soggetti
Physycs, Mathematical","Phsycs, Fluid & Plasmas
ISSN journal
1063651X
Volume
56
Issue
1
Year of publication
1997
Part
B
Pages
770 - 779
Database
ISI
SICI code
1063-651X(1997)56:1<770:PIALMA>2.0.ZU;2-B
Abstract
A vector model on the simple cubic lattice, describing a mixture of wa ter, oil, and amphiphile, is considered. An integration over the amphi phile orientational degrees of freedom is performed exactly in order t o obtain an effective Hamiltonian for the system. The resulting model is a three-state (spin-1) system and contains many-site interaction te rms. The analysis of the ground state reveals the presence of the wate r-oil-rich phase as well as the amphiphile-rich and the cubic phases. The temperature phase diagram of the system is analyzed in a local mea n-field approach, and a triple line of water-rich, oil-rich, and micro emulsion coexistence is obtained. For some values of the model paramet ers, lamellar phases also appear in the system, but only at finite tem perature. The Lifshitz line is determined in a semianalytical way in o rder to locate the microemulsion region of the disordered phase.