Observation of plasmons in 2-D organic metal BO2.4I3 by reflection spectroscopy

Citation
J. Ulanski et al., Observation of plasmons in 2-D organic metal BO2.4I3 by reflection spectroscopy, SYNTH METAL, 120(1-3), 2001, pp. 721-722
Citations number
7
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
120
Issue
1-3
Year of publication
2001
Pages
721 - 722
Database
ISI
SICI code
0379-6779(20010315)120:1-3<721:OOPI2O>2.0.ZU;2-H
Abstract
For the first time the plasmon in 2-D organic metal BO2.4I3 was observed by means of reflection method. The new unknown peak in the near-infrared regi on at 5000 cm(-1) was observed in the specular reflection normal to the ((1 ) over bar 01) crystal face, which makes an angle of 67.0 degrees with the conducting sheet. Such spectrum can be theoretically simulated using the pr incipal dielectric function for a two-dimensional metal. The simulated spec trum agrees well with the experimental one, proving that this new peak is d ue to the plasmon absorption. Similar plasmon absorption we have observed f or BO2Cl(H2O)(3) crystal.