Citation
H. Aso et al., Doping effect on MX-chain compound, SYNTH METAL, 120(1-3), 2001, pp. 775-776
Citations number
4
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779
→ ACNP
Volume
120
Issue
1-3
Year of publication
2001
Pages
775 - 776
Database
ISI
SICI code
0379-6779(20010315)120:1-3<775:DEOMC>2.0.ZU;2-M
Abstract
The {[Pt(en)(2)] [PtBr2(en)(2)]}(3)(CuBr4)(4) which consists of the double
chain structures of the main one-dimensional Pt(II)-Pt(IV) chain and one-di
mensional counteranion of trigonal bipyramidal Cu(I) ions, is doped with Br
-2. The intensities of d-d transitions and ESR spectra in Cu(II) species in
counteranions increase as increase of exposure time. Accordingly, the indu
ced Pt(III) species attributable to neutral solitons are considered to incr
ease in the main chain by doping.