Oxygen-substituted derivatives of DHTTF-fused donors: synthesis and properties

Authors
Yamada, J Kawagishi, S Shinomaru, T Akutsu, H Nakatsuji, S Nishikawa, H Ikemoto, I Kikuchi, K
Citation
J. Yamada et al., Oxygen-substituted derivatives of DHTTF-fused donors: synthesis and properties, SYNTH METAL, 120(1-3), 2001, pp. 787-788
Citations number
6
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
120
Issue
1-3
Year of publication
2001
Pages
787 - 788
Database
ISI
SICI code
0379-6779(20010315)120:1-3<787:ODODDS>2.0.ZU;2-J
Abstract
The synthesis and electrochemical properties of novel oxygen-containing pi -electron donors (3a,b and 4), in which only one outer sulfur atom of the D HTTF (dihydrotetrathiafulvalene)-fused donors (1a,b and 2) is replaced by o xygen atom, has been investigated to explore new organic metals. Among the 3a-based CT (charge-transfer) complexes and salts, the TCNQ (tetracyanoquin odimethane) complex and the BF4 salt exhibited metallic conducting behavior .