A new family of conducting and magnetic charge-transfer salts from BMDT-TTF

Authors
Mas-Torrent, M Turner, SS Wurst, K Vidal-Gancedo, J Veciana, J Rovira, C Day, P
Citation
M. Mas-torrent et al., A new family of conducting and magnetic charge-transfer salts from BMDT-TTF, SYNTH METAL, 120(1-3), 2001, pp. 799-800
Citations number
5
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
120
Issue
1-3
Year of publication
2001
Pages
799 - 800
Database
ISI
SICI code
0379-6779(20010315)120:1-3<799:ANFOCA>2.0.ZU;2-T
Abstract
Crystals suitable for X-ray structure determination have been obtained from the electrocrystallisation of BMDT-TTF donor, bis(methylenedithio)tetrathi afulvalene, with (N-quinolinium)[Cr(NCS)(4)(quinoline)(2)], although, due t o a ligand exchange during the electrocrystallisation, it has been found th at the product is in fact (BMDT-TTF)(4)[Cr(NCS)(6)]. In this salt the anion s and the donors form segregated layers. A salt from BMDT-TTF and (N-isoqui nolinium)[Cr(NCS)(4)(isoquinoline)(2)] has also been prepared. Raman, EPR a nd NIR measurements have also been carried out.