Partially-oxidized Ni(dmit)(2) salt with copper ions

Authors
Sakai, K Akutagawa, T Hasegawa, T Nakamura, T
Citation
K. Sakai et al., Partially-oxidized Ni(dmit)(2) salt with copper ions, SYNTH METAL, 120(1-3), 2001, pp. 805-806
Citations number
7
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
120
Issue
1-3
Year of publication
2001
Pages
805 - 806
Database
ISI
SICI code
0379-6779(20010315)120:1-3<805:PNSWCI>2.0.ZU;2-K
Abstract
The d-pi hybrid charge-transfer system, Cu-0.39[Ni(dmit)(2)] was prepared, and the crystal and electronic band structures were investigated. In the cr ystal, a unique layered structure is constructed, which results from the st acks of dimerized Ni(dmit)(2) being largely slipped along the long molecula r axis. The copper ions are located at the interlayer spaces with large the rmal factors. From the tight-binding band calculation, a quasi-one-dimensio nal Fermi surface was obtained.