Preparation and characterization of novel organic radical anions for organic conductors: TEMPO-NHSO3- and TEMPO-OSO3-

Authors
Akutsu, H Yamada, J Nakatsuji, S
Citation
H. Akutsu et al., Preparation and characterization of novel organic radical anions for organic conductors: TEMPO-NHSO3- and TEMPO-OSO3-, SYNTH METAL, 120(1-3), 2001, pp. 871-872
Citations number
9
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
120
Issue
1-3
Year of publication
2001
Pages
871 - 872
Database
ISI
SICI code
0379-6779(20010315)120:1-3<871:PACONO>2.0.ZU;2-G
Abstract
The preparation and characterization of new organic radical anions TEMPO-NH SO3- (tsfa) and TEMPO-OSO3- (tosu), which consist of the organic stable rad ical (TEMPO) and the anionic functional group (-NHSO3- or -OSO3-), has been investigated. The molecular and crystal structures of bis(triphenylphospho ranylidene)ammonium determined by X-ray analysis indicate that tsfa exists as a monovalent anion. Black powders of the TTF(.)tsfa and TTF(.)tosu salts were obtained, in each of which the donor to anion ratio is found to be 1 : 1 by elemental analysis. TTF(.)tsfa shows a weak antiferromagnetic intera ction with C = 0.360 emu M mol(-1) and theta = -0.52 K.