Synthesis, electrical properties of a novel Ni-dithiolene complex with dimerized structure

Authors
Kobayashi, N Naito, T Inabe, T
Citation
N. Kobayashi et al., Synthesis, electrical properties of a novel Ni-dithiolene complex with dimerized structure, SYNTH METAL, 120(1-3), 2001, pp. 1055-1056
Citations number
5
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
120
Issue
1-3
Year of publication
2001
Pages
1055 - 1056
Database
ISI
SICI code
0379-6779(20010315)120:1-3<1055:SEPOAN>2.0.ZU;2-I
Abstract
A novel dimerized Ni-dithiolene complex, (n-Bu4N)(2)[Ni(dmit)(i-mnt)](2), w as synthesized and characterized by X-ray structure analysis. In this compl ex two [Ni(dmit)(i-mnt)l units were mutually connected by two long axial Ni -S bonds. The single crystals of BEDT-TTF and TTF salts with [Ni(dmit)(i-mn t)](2)(2-) were prepared by electrocrystallization and characterized by X-r ay analysis. The Ni-S bonds of each dimer were also retained in both salts. Both salts exhibited semiconducting behavior with the room-temperature res istivity rho (rt) / Omega cm = 10(2), 10(3), respectively.