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Electroreduction of aryl-dichlorides or -dibromides in an electrochemical c
ell fitted with a sacrificial zinc anode and in the presence of cobalt hali
des as catalyst in acetonitrile/pyridine as solvent affords the correspondi
ng organodizinc species in moderate to excellent yields with high selectivi
ty. (C) 2001 Elsevier Science Ltd. All rights reserved.