An enantiospecific synthesis of (-)-2-pupukeanone via a rhodium carbenoid C-H insertion reaction

Authors
Srikrishna, A Kumar, PR Gharpure, SJ
Citation
A. Srikrishna et al., An enantiospecific synthesis of (-)-2-pupukeanone via a rhodium carbenoid C-H insertion reaction, TETRAHEDR L, 42(23), 2001, pp. 3929-3931
Citations number
14
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
23
Year of publication
2001
Pages
3929 - 3931
Database
ISI
SICI code
0040-4039(20010604)42:23<3929:AESO(V>2.0.ZU;2-P
Abstract
An enantiospecific synthesis of (-)-2-pupukeanone. starting from (R)-carvon e employing a Michael Michael I reaction and an intramolecular rhodium carb enoid C H insertion reaction as: the key steps for the generation of the is otwistane. framework, is described. (C) 2001 Elsevier Science Ltd. All ligh ts reserved.