UNUSUAL SPIN-SPIN INTERACTIONS ACROSS THE COORDINATION BOND IN HEXACOORDINATE SILICON COMPLEXES - CRYSTAL-STRUCTURE COUPLING RELATIONSHIP

Authors
KALIKHMAN I KRIVONOS S STALKE D KOTTKE T KOST D
Citation
I. Kalikhman et al., UNUSUAL SPIN-SPIN INTERACTIONS ACROSS THE COORDINATION BOND IN HEXACOORDINATE SILICON COMPLEXES - CRYSTAL-STRUCTURE COUPLING RELATIONSHIP, Organometallics, 16(15), 1997, pp. 3255-3257
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
15
Year of publication
1997
Pages
3255 - 3257
Database
ISI
SICI code
0276-7333(1997)16:15<3255:USIATC>2.0.ZU;2-P
Abstract
Two-, three-, and even four-bond coupling constants are reported for t he first time across the N-->Si coordination bond in. neutral, hexacoo rdinate silicon chelates. Two-bond coupling constants depend criticall y on bond angles, and three-bond couplings follow a Karplus-type corre lation with dihedral angles obtained from X-ray crystallographic analy ses.