Evaluation of chemical protective clothing by FT-IR/ATR spectroscopy

An attenuated total reflectance (ATR) permeation cell has been used to eval uate the permeation of polymer samples from chemical protective clothing (C PC), mainly gloves, by several chemical types including a solvent, a commer cial pesticide mix, and a volatile solid. Good contact between sample and A TR crystal was ensured by the use of low gas pressure. The passage of the c hemicals through the CPC sample could be readily followed by analysis of se ts of Fourier transform infrared (FT-IR) spectra measured during permeation experiments. Diffusion coefficients could only be estimated. The ATR metho d is compared with the traditional two-compartment cell used for evaluation of CPC, and its advantages and disadvantages are discussed.