A. Tarre et al., Comparative study of low-temperature chloride atomic-layer chemical vapor deposition of TiO2 and SnO2, APPL SURF S, 175, 2001, pp. 111-116
Peculiarities of the atomic-layer chemical vapor deposition growth of TiO2
and SnO2 thin films from chlorides and water at low (less than or equal to
300 degreesC) temperatures are in situ monitored on a submonolayer scale by
incremental dielectric reflection. RHEED, AES, EPMA, SFM, and UV-VIS spect
rophotometry are used for the ex situ characterization of the growth. It is
shown that the main peculiarity of the TiO2 growth exhibits itself in the
spontaneous crystallization at the very beginning of the deposition while t
he peculiarity of the SnO2 growth is connected with a low reactivity of wat
er. (C) 2001 Elsevier Science B.V. All rights reserved.