Optical spectroscopies: Raman, infrared (IR) and photoluminescence (PL) wer
e used to investigate the influence of the substrate temperature on the him
formation of the organic molecule 3,4,9,10-perylenetetracarboxyl dianhydri
de (PTCDA) on hydrogen-passivated silicon(1 0 0) substrates. Raman spectra
exhibit four phonon bands below 125 cm(-1), indicating the crystalline natu
re of the films. The spectral changes of both Raman- and infrared-active mo
des reflect that the size of the individual crystals increases with the sub
strate temperature during growth. Moreover, they support an increase in the
content of the alpha -phase at the expense of the beta -phase. The rising
background in the high frequency range of the Raman spectra is related to a
n enhancement of the PL efficiency connected to a reduced number of non-rad
iative centres of recombination. Time-resolved PL measurements reveal that
the PL decay time increases with the substrate temperature, approaching the
value characteristic for a PTCDA single crystal. (C) 2001 Elsevier Science
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