SYNTHESIS AND CHARACTERIZATION OF UNSYMMETRICAL CIS-(PHOSPHINO-PHOSPHOLYL)ETHENE TETRACARBONYL MOLYBDENUM COMPLEXES - HYDROPHOSPHINATION REACTIONS OF (HC-CCH2PPH2)MO(CO)(5) AND (HC-CCH2DBP)MO(CO)(5)

Authors
MAITRA K CATALANO VJ NELSON JH
Citation
K. Maitra et al., SYNTHESIS AND CHARACTERIZATION OF UNSYMMETRICAL CIS-(PHOSPHINO-PHOSPHOLYL)ETHENE TETRACARBONYL MOLYBDENUM COMPLEXES - HYDROPHOSPHINATION REACTIONS OF (HC-CCH2PPH2)MO(CO)(5) AND (HC-CCH2DBP)MO(CO)(5), Bulletin de la Societe chimique de France, 134(5), 1997, pp. 471-486
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
134
Issue
5
Year of publication
1997
Pages
471 - 486
Database
ISI
SICI code
0037-8968(1997)134:5<471:SACOUC>2.0.ZU;2-K
Abstract
The base-catalyzed hydrophosphination reactions of (HC drop CCH2PPh2)M o(CO)(5) and (HC drop CCH2DBP)Mo(CO)(5) with (Ph-2 PH)Mo(CO)(5) and (D BPH)Mo(CO)(5) give several different products as a function of reactio n conditions. These products were characterized by elemental analyses, physical properties,H-1, C-13{H-1}, and P-31{H-1} NMR spectroscopy, i nfrared spectroscopy, and in several cases by X-ray crystallography.