SYNTHESIS AND CHARACTERIZATION OF UNSYMMETRICAL CIS-(PHOSPHINO-PHOSPHOLYL)ETHENE TETRACARBONYL MOLYBDENUM COMPLEXES - HYDROPHOSPHINATION REACTIONS OF (HC-CCH2PPH2)MO(CO)(5) AND (HC-CCH2DBP)MO(CO)(5)
K. Maitra et al., SYNTHESIS AND CHARACTERIZATION OF UNSYMMETRICAL CIS-(PHOSPHINO-PHOSPHOLYL)ETHENE TETRACARBONYL MOLYBDENUM COMPLEXES - HYDROPHOSPHINATION REACTIONS OF (HC-CCH2PPH2)MO(CO)(5) AND (HC-CCH2DBP)MO(CO)(5), Bulletin de la Societe chimique de France, 134(5), 1997, pp. 471-486
The base-catalyzed hydrophosphination reactions of (HC drop CCH2PPh2)M
o(CO)(5) and (HC drop CCH2DBP)Mo(CO)(5) with (Ph-2 PH)Mo(CO)(5) and (D
BPH)Mo(CO)(5) give several different products as a function of reactio
n conditions. These products were characterized by elemental analyses,
physical properties,H-1, C-13{H-1}, and P-31{H-1} NMR spectroscopy, i
nfrared spectroscopy, and in several cases by X-ray crystallography.