SYNTHESIS OF NEW BIS BIDENTATE LIGANDS - CATALASE ACTIVITIES OF THE CORRESPONDING BIS(1,3-DIKETONATO)IRON(III) COMPLEXES

Authors
PROVENT C CHAUTEMPS P GELLON G PIERRE JL
Citation
C. Provent et al., SYNTHESIS OF NEW BIS BIDENTATE LIGANDS - CATALASE ACTIVITIES OF THE CORRESPONDING BIS(1,3-DIKETONATO)IRON(III) COMPLEXES, Bulletin de la Societe chimique de France, 134(5), 1997, pp. 487-493
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
134
Issue
5
Year of publication
1997
Pages
487 - 493
Database
ISI
SICI code
0037-8968(1997)134:5<487:SONBBL>2.0.ZU;2-Q
Abstract
The syntheses of five new tetradentate ligands of bis(1,3-diketonate) type are described. The two diketonate moieties are connected by vario us long-chain spacers which allow the folding of the ligands for the f ormation of bis(1,3-diketonato)iron(III) complexes. These complexes ex hibit, in the presence of imidazole, a catalytic activity towards the decomposition of hydrogen peroxide (catalase activity).