REACTION OF ALPHA-HALOGENOESTER CARBANIONS WITH CATIONIC (ETA(6)-ARENE) TRICARBONYLMANGANESE COMPLEXES

Authors
BALSSA F GAGLIARDINI V LECORRESUSANNE C ROSEMUNCH F ROSE E VAISSERMAN J
Citation
F. Balssa et al., REACTION OF ALPHA-HALOGENOESTER CARBANIONS WITH CATIONIC (ETA(6)-ARENE) TRICARBONYLMANGANESE COMPLEXES, Bulletin de la Societe chimique de France, 134(5), 1997, pp. 537-541
Citations number
45
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
134
Issue
5
Year of publication
1997
Pages
537 - 541
Database
ISI
SICI code
0037-8968(1997)134:5<537:ROACWC>2.0.ZU;2-K
Abstract
The reaction of methyl 2-lithio 2-chloro and 2-lithio 2-bromopropanoat e with cationic (arene)tricarbonylmanganese complexes affords the corr esponding neutral (eta(5)-cyclohexadienyl) tricarbonyl complexes. Only one regioisomer is observed in the case of toluene and anisole comple xes. The X-ray analysis of the complex due to the addition of methyl 2 -lithio 2-chloropropanoate to the (benzene) manganese complex is repor ted.