METAL-SUPPORT INTERACTIONS IN THE CATALYTIC-OXIDATION OF CARBON-MONOXIDE

Citation
Np. Siswana et Dl. Trimm, METAL-SUPPORT INTERACTIONS IN THE CATALYTIC-OXIDATION OF CARBON-MONOXIDE, Catalysis letters, 46(1-2), 1997, pp. 27-29
Citations number
17
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
1011372X
Volume
46
Issue
1-2
Year of publication
1997
Pages
27 - 29
Database
ISI
SICI code
1011-372X(1997)46:1-2<27:MIITCO>2.0.ZU;2-L
Abstract
The catalytic oxidation of carbon monoxide has been studied over trans ition metal oxides in the absence and presence of platinum. A characte ristic activity pattern was observed in both cases, with platinum redu cing the temperature at which oxidation was initiated by between 20 an d 200 K. The results show that platinum-metal oxide interactions are i mportant in the system. These appear to involve the reaction of carbon monoxide adsorbed on the metal with oxygen associated with the metal oxide lattice.