The composting of high organic content wastes has been shown to produce nit
rous oxide (N2O). This study was initiated to investigate the mechanisms of
N2O emissions from aerated composting and to determine the optimal operati
onal conditions that minimize N2O emissions. The results of our experiment
in laboratory-scale composters showed that more than 95% of N2O was produce
d during the later period of composting when readily available carbon sourc
es had been depleted. Significant increases in N2O emission after nitrite (
NO2-) addition, and good NO2- - N2O correlation, indicates that N2O was tra
nsformed from NO2-. Extremely high N2O generation was observed after NO2- a
ddition in the presence and absence of composted cattle manure. This sugges
ts an identical mechanism for N2O production in both treatments. However, t
he addition of composted cattle manure resulted in an earlier initiation of
the main N2O generation period. Intermittent feeding of fresh food waste p
ostponed the main N2O generation period, and reduced the mass-based N2O emi
ssions by 20%.