Removal of naphthalene, phenanthrene, and pyrene by sorbents from hot gas

It is the first time that the removal of polycyclic aromatic hydrocarbons ( PAH) containing different aromatic rings number [naphthalene (Np), phenanth rene (Phe), and pyrene (Py)l from combustion hot gas has been carried out. The aim was to relate the sorbents textural characteristics with the adsorp tion capacity of these 2-4-ring PAH at the conditions emitted at energy gen eration. The sorbents textural parameters [total micropore volume (V-N2), n arrow micropore volume (V-CO2), mesopore volume (V-BJH), and the free activ e sites] were analyzed trying to correlate them with their Np, Phe, and Py adsorption capacities. To get this aim, single and multiple linear regressi ons (MLR) were applied to the three PAH. A principal component analysis was performed to generate new and uncorrelated variables. It enabled us to sho w that the relations between the textural parameters were analyzed using a principal components regression (PCR). The PCR analysis had a good statisti cal quality, but neither did it allow differentiating free active site type s nor did VN, and Vco,. The correlations were thus set up applying a MLR to the original variables The regression statistical quality was similar to t he PCR analysis, and it could give an easier explanation of the parameters that affected the adsorption. In Np adsorption, the 87% data variance was e xplained, and the adsorption was positively correlated to Vco, and the micr opore mean diameter (L). In the Phe regression there was 98% variance expla ined, and its adsorption was positively correlated to the VN2 and the micro pore distribution, n. Finally, in the Py adsorption, the 96% data variance was explained, and this adsorption was positively correlated to V-N2 and V- BJH These dependencies were according to the molecular parameters of these compounds (molecular diameter and volatility) because the higher the number of aromatic rings of the PAH, the more favored the adsorbate-adsorbate int eractions. Besides, the higher the mean diameter micropores, the lower the diffusional problems showed by Np, Phe, and Py.