R. Garriga et al., Thermodynamic excess properties for binary mixtures of 1-chlorobutane with2-butanol or 2-methyl-1-propanol, FLU PH EQUI, 181(1-2), 2001, pp. 203-214
Vapour pressures of 1-chlorobutane + 2-butanol, or 1-chlorobutane + 2-methy
l-1-propanol at 10 temperatures between 278.15 and 323.15 K were measured b
y a static method. Excess molar enthalpies and volumes were also measured a
t 298.15 K. Reduction of the vapour pressure data to obtain activity coeffi
cients and excess molar Gibb energies was carried out by fitting the vapour
pressure data to the Redlich-Kister correlation according to Barker's meth
od. In very diluted alcohol mixtures, and for both systems, azeotropic mixt
ures with a minimum boiling temperature were observed. (C) 2001 Elsevier Sc
ience B.V. All rights reserved.