Macroporous Si was prepared by electrochemical etching at a linearly varyin
g applied voltage. A relationship between the process parameters (illuminat
ion intensity, current density, and applied voltage) was derived in a diffu
sion-drift model. The experimental dependences of the ratio of the photohol
e concentration to the current density on the distance between the illumina
ted surface and pore bottom were shown to agree with the diffusion-drift mo
del for nonequilibrium-hole transport provided that the anode thickness exc
eeds the diffusion length of holes and the pore radius is comparatively lar
ge. The photonic band gap of the two-dimensional macroporous Si structure w
as calculated by the plane-wave method. The transmittance of macroporous Si
was measured. The effect of surface recombination on the lifetime of noneq
uilibrium charge carriers was assessed.