A modified low-temperature solvent crystallization process was employed for
the enrichment of polyunsaturated fatty acids (PUFA) in borage and linseed
oil fatty acids. The effects of solvent, operation temperature, and solven
t to free fatty acid (FFA) ratio on the concentration of PUFA were investig
ated. The best results were achieved when a mixture of 30% acetonitrile and
70% acetone was used as the solvent. With an operation temperature of -80
degreesC and a solvent to FFA ratio of 30 mL/g, gamma -linolenic acid (GLA)
in FFA of saponified borage oil can be raised from 23.4 to 88.9% with a yi
eld of 62.0%. At a yield of 24.9%, alpha -linolenic acid in linseed oil can
be increased from 55.0 to 85.7%. The results of this work are comparable t
o the best results available in the literature.