Poly(propylene) compounds containing organophilic layered nanosilicates wer
e prepared by means of melt extrusion at 210 degreesC in order to investiga
te the influence of maleic anhydride-grafted poly(propylene) (PP-g-MA) as a
compatibilizer on morphology development and rheological properties. It wa
s found that the addition of PP-g-MA leads to the strong exfoliation of sil
icate layers within the matrix as investigated by WAXS. This process is ass
ociated with the build up of an unstable morphology as probed by dynamic rh
eology and with the violation of the time-temperature superposition princip
le. Annealing of the samples at extrusion temperature level leads to a coar
sening of the silicate superstructure and further improvement of the exfoli
ation at the same time. This process results in a stable morphology with un
ique rheological properties indicating network-like superstructure of silic
ate layers.