PI-FACIAL DIASTEREOSELECTION IN REDUCTIONS OF STERICALLY UNBIASED KETONES CONTAINING THE NORBORNYL FRAMEWORK - FURTHER TESTS FOR THEORETICAL-MODELS

Authors
MEHTA G KHAN FA GANGULY B CHANDRASEKHAR J
Citation
G. Mehta et al., PI-FACIAL DIASTEREOSELECTION IN REDUCTIONS OF STERICALLY UNBIASED KETONES CONTAINING THE NORBORNYL FRAMEWORK - FURTHER TESTS FOR THEORETICAL-MODELS, Perkin transactions. 2, (11), 1994, pp. 2275-2277
Citations number
18
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
11
Year of publication
1994
Pages
2275 - 2277
Database
ISI
SICI code
0300-9580(1994):11<2275:PDIROS>2.0.ZU;2-A
Abstract
Ketones 3a-c exhibit syn-face selectivity in borohydride reduction; MN DO and ah initio calculations on model and realistic transition states , respectively, reproduce the preference, but differ on the role of el ectrostatic and orbital effects.